Run multiple Skype accounts on Windows.

To use more than one Skype account on the same computer at the same time, you need to start a new instance of Skype.
Lets see how :

METHOD 1
1. Open Run (Press Win + R Key).
2. In Run, type or Copy below command and press OK,

 For 32-bit operating systems:
   "C:\Program Files\Skype\Phone\Skype.exe" /secondary

 For 64-bit operating systems:
   "C:\Program Files (x86)\Skype\Phone\Skype.exe" /secondary

NOTE : If you’ve changed the installation path for Skype, then you’ll need to enter the correct path for the Skype.exe file.

3. Other instance of Skype will open on your windows, Login and enjoy.

METHOD 2
1. Go to below location, Find "Skype.exe" Right-click it and select Send to > Desktop (create shortcut).

 For 32-bit operating systems:
   "C:\Program Files\Skype\Phone\Skype.exe" /secondary

 For 64-bit operating systems:
   "C:\Program Files (x86)\Skype\Phone\Skype.exe" /secondary

2. Now, right-click on the shortcut and select Properties. In the Target field of the Shortcut tab, add /secondary to the end of the path. The Target field will now be "C:\Program Files\Skype\Phone\Skype.exe" /secondary.

3. Click OK to save the changes.

4. Just execute the shortcut every time you login to multiple Skype account.

Enjoy! and Stay Connected.